You will need to decide what user ID will be used to run the export. That user ID will need full access permissions to the mailboxes in order to export them successfully. Assign the correct permissions to the OU by running the following command;
get-mailbox -OrganizationalUnit "OU Name"|Add-MailboxPermission -User "UserName" -AccessRights FullAccess
You are now ready to run the export. Make sure to specify the correct OU and target directory.
get-mailbox -OrganizationalUnit "OU Name"|Export-Mailbox -PSTFolderPath "Target Directory"
This will export all mailboxes in the specified OU. The process is multithreaded and will export four mailboxes simultaneously.
Nice Information about How to Export mailbox to PST exchange 2007. There are many tools available in the online market, but you can use a Third Party Exchange Recovery software which provides a perfect solution to Export exchange 2007 mailbox to PST format.
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